Bis(2-bromobenzyl) ether
نویسندگان
چکیده
In the title compound, C14H12Br2O, the dihedral angle between the aromatic rings is 2.7 (3)° and the Br atoms lie on the same side of the mol-ecule. No inter-molecular inter-actions occur in the crystal beyond van der Waals contacts.
منابع مشابه
Bis(2-bromobenzyl) trisulfide
The title mol-ecule, C(14)H(12)Br(2)S(3), lies on a crystallographic twofold rotation axis which bis-ects the S-S-S angle. The dihedral angle between the two symmetry-related benzene rings is 89.91 (9)°. In terms of hybridization principles, the S-C-C angle is slightly larger than expected.
متن کامل1,2-Bis(2-bromobenzyl)diselane
In the title compound, C(14)H(12)Br(2)Se(2), the Se-Se bond length [2.3034 (9) Å] is similar to those in diphenyl diselenide [2.3066 (7) and 2.3073 (10) Å] and shorter than that in 1,8-diselenona-phthalene [2.0879 (8)Å]. The mol-ecule adopts a classical gauche conformation.
متن کاملTriethylene Glycol BW 112-27-6 _03-04-09_x
TEG 1 Triethylene Glycol (CAS# 112-27-6) (Synonyms: 2,2'-(1,2-Ethanediylbis(oxy))bisethanol; 1,2-Bis(2-hydroxyethoxy)ethane; 2,2'Ethylenedioxybis(ethanol); 2,2'-Ethylenedioxydiethanol; 2,2'-Ethylenedioxyethanol; 3,6Dioxaoctane-1,8-diol; Bis(2-hydroxyethoxyethane); Di-beta-hydroxyethoxyethane; Ethanol, 2,2'(1,2-ethanediylbis(oxy))bis-; Ethanol, 2,2'-(ethylenedioxy)di-; Ethylene glycol dihydroxyd...
متن کاملSOME GLyelDYL ETHERS
Chem. Abstr. Services Reg. No.: 1675-54-3 Chem. Abstr. Name: 2,2' -r (I-Methylethylidene )bis( 4, I-phenyleneoxyethylene) )bis(oxiane) . IUPAC Systematic Name: 2,2'-r(1-Methylethylidene)bis(4,i-phenyleneoxyethylene) )bis( oxiane ) Synonym: 4,4' -Bis(2,3-epoxyropoxy)diphenyldimethylmethane; 2,2-bisfpara-(2,3epoxyropoxy)phenyl)propane; 2,2-bisr 4-(2,3-epoxyropoxy)phenyl)propane; bis( 4glycidyloxy...
متن کاملReduction of Bromo- and Iodo-2,6-bis(diphenylphosphanylmethyl)benzene with Magnesium and Calcium
Arylmagnesium and -calcium reagents are easily accessible; however, ether degradation processes limit storability, especially of the calcium-based heavy Grignard reagents. Ortho-bound substituents with phosphanyl donor sites usually block available coordination sites and stabilize such complexes. The reaction of bromo-2,6-bis(diphenylphosphanylmethyl)benzene (1a) with magnesium in tetrahydrofur...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014